Shanxi gradually gained the upper hand in the second quarter before going eight points up at the break.
The French champions will kick off the continental campaign at home against Manchester United on October 20.
Cadiz had lost their previous 13 league visits to Athletic Bilbao.
She lapped in under 45 seconds on a 1,100-meter-long indoor driveway and overtook other competitors before the end. And it cost her 50 yuan (about 7.36 U.S. dollars) for the six-minute drive.
Shan said her on-fire shooting performance was derived from confidence.
"We had a poor start as our players didn't show enough mentality, but I'm satisfied with the players' performance in the following three quarters," Shaanxi coach Jiang E'Ying commented.
Luis Enrique has handed a first call up to Levante midfielder, Jose Campana, while recalling Dani Caballos (Arsenal) and Sergio Canales (Betis) to a 25-man squad.
The 2018 champion lost to Anisimova in the quarterfinals in Paris last year, but this time the Romanian needed only 54 minutes to complete a convincing victory.
Wang Lili made 11 of 20 field shots and scored 25 points for Xinjiang, one of the title contenders over the current campaign. Wang Siyu helped with 11.
On the Hebei side, Guo bagged a team-high 19 points. Ma Wen and Zhang Yaqi scored 13 and 12 points respectively.
Shanxi had a 10-3 dash in the midway of the last quarter, bringing the game beyond Hebei's reach.